Thank you very much for your advice and information. I modified the coordinates, but I have still some problems.
1) layer 1
Horizontal coordinate system
Geographic coordinate system name: GCS_WGS_1984
Details
Geographic Coordinate System
Latitude Resolution: 0.000000
Longitude Resolution: 0.000000
Geographic Coordinate Units: Decimal degrees
Geodetic Model
Horizontal Datum Name: D_WGS_1984
Ellipsoid Name: WGS_1984
Semi-major Axis: 6378137.000000
Denominator of Flattening Ratio: 298.257224
_________________
Bounding coordinates
Horizontal
In decimal degrees
West: 10.385948
East: 12.477436
North: 47.091793
South: 45.673069
In projected or local coordinates
Left: 10.385948
Right: 12.477436
Top: 47.091793
Bottom: 45.673069
2) layer 2
Horizontal coordinate system
Projected coordinate system name: WGS_1984_UTM_Zone_32N
Geographic coordinate system name: GCS_WGS_1984
Details
Grid Coordinate System Name: Universal Transverse Mercator
UTM Zone Number: 32
Transverse Mercator Projection
Scale Factor at Central Meridian: 0.999600
Longitude of Central Meridian: 9.000000
Latitude of Projection Origin: 0.000000
False Easting: 500000.000000
False Northing: 0.000000
Planar Coordinate Information
Planar Distance Units: meters
Coordinate Encoding Method: coordinate pair
Coordinate Representation
Abscissa Resolution: 0.000000
Ordinate Resolution: 0.000000
Geodetic Model
Horizontal Datum Name: D_WGS_1984
Ellipsoid Name: WGS_1984
Semi-major Axis: 6378137.000000
Denominator of Flattening Ratio: 298.257224
_________________
Bounding coordinates
Horizontal
In decimal degrees
West: 10.362326
East: 12.504936
North: 47.129382
South: 45.640333
In projected or local coordinates
Left: 606088.187500
Right: 766033.625000
Top: 5220491.203121
Bottom: 5059756.878740
I can see the map with the two layers, but the borders don't coincide. (layer 1 represents municipalities, layers 2 represents the provinces where those municipalities are located)
I also changed layer 2 in GCS_WGS_1984 but I have still the same problem, that is, borders don't overlap.
2bis) layer 2
Horizontal coordinate system
Geographic coordinate system name: GCS_WGS_1984
Details
Geographic Coordinate System
Latitude Resolution: 0.000000
Longitude Resolution: 0.000000
Geographic Coordinate Units: Decimal degrees
Geodetic Model
Horizontal Datum Name: D_WGS_1984
Ellipsoid Name: WGS_1984
Semi-major Axis: 6378137.000000
Denominator of Flattening Ratio: 298.257224
_________________
Bounding coordinates
Horizontal
In decimal degrees
West: 10.387225
East: 12.478793
North: 47.093540
South: 45.674821
In projected or local coordinates
Left: 10.387225
Right: 12.478793
Top: 47.093540
Bottom: 45.674821
Is there anything else I can possibly do?
Thank you.
Giorgia