When I debug it in python 2.7.3 I see these two errors, shown in the image here [ATTACH=CONFIG]33625[/ATTACH]
I get a similar debugger error when I run a script for synchronizing as well. I was trying to learn from the simple start script sample given but seems to not work (nothing gets logged). I tried running as administrator as well as the final posting commenter wrote and still no luck. I have even changed the path to use UNC paths as well and still no luck. What do these 'bdb'. run error and the <module>(),line10:import arcinfo errors mean and how to fix them? No idea where to begin, any guidance or direction would help greatly.
At a guess, I'd say that you don't have your paths set up correctly. That's what the error for line 1, import sys suggests. Python can't find the sys module.
I have uninstalled python, repaired arcgis desktop 10.2 installation, removed arcgis desktop 10.2 and then re-installed and still having issues with arcpy not importing.