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Hi,
I would suggest you to go through tutorial exercise 1,
http://resources.arcgis.com/en/help/main/10.1/#/Exercise_1_Creating_a_network_dataset/00470000005t00...
download the tutorial data and use SanDiego.gdb or SanFrancisco.gdb as examples.
http://www.arcgis.com/home/item.html?id=d6bd91b2fddc483b8ccbc66942db84cb
The source data must have time and distance fields on street feature class so you can use VRP solver.
Please feel free to let me know if you need more help.
Thanks.
Anna