You can wrap a code block in code tags when you place it in the message window It makes it easier to read
import arcpy
#Set geoprocessing environment
arcpy.env.workspace = "H:\Dr. Hines\New File Geodatabase.gdb"
arcpy.env.overwriteOutput = True
#Create list of all blocks
fcList = arcpy.ListFeatureClasses("*blk00")
#Create loop
for fc in fcList:
      blk = fcLis
      arcpy.SelectLayerByLocation_management("Analysis Roads","HAVE_THEIR_CENTER_IN")
      for fc in fcList:
           rows = arcpy.InsertCursor(blk)
           row = rows.newRow()
           row.STFID = ()
           fieldVal = row.getValue("STFID")
           arcpy.CalculateField_management("Analysis Roads","STFID","fieldVal")
import arcpy
#Set geoprocessing environment
arcpy.env.workspace = "H:\Dr. Hines\New File Geodatabase.gdb"
arcpy.env.overwriteOutput = True
#Create list of all blocks
fcList = arcpy.ListFeatureClasses("*blk00")
#Create loop
for fc in fcList:
      selected = arcpy.SelectLayerByLocation_management("Analysis Roads","HAVE_THEIR_CENTER_IN", fc)
      highway = "Analysis Roads"
      rows = arcpy.UpdateCursor(higway)
          for row in rows:
              if row is in selected:
                  row.STFID = fc.STFID #this is assuming your feature classes have a STFID field too, you can change this to the right field name. 
                  rows.updateRow(row) 
import arcpy
#Set geoprocessing environment
arcpy.env.workspace = r"H:\Dr. Hines\New File Geodatabase.gdb" # \ is an escape character in python strings and needs the raw flag or to be doubled to act as a character
arcpy.env.overwriteOutput = True
#Create list of all blocks
fcList = arcpy.ListFeatureClasses("*blk00")
#Create loop
for fc in fcList:
      blk = fcLis # Looks like a misspelling.  Shouldn't this be fcList
      arcpy.SelectLayerByLocation_management("Analysis Roads","HAVE_THEIR_CENTER_IN")
      for fc in fcList: # this is bad.  Never loop the same object within a loop of itself.  Create a new list object to loop if you need an embedded loop.
           rows = arcpy.InsertCursor(blk)
           row = rows.newRow()
           row.STFID = ()
           fieldVal = row.getValue("STFID")
           arcpy.CalculateField_management("Analysis Roads","STFID","fieldVal")
>>> import arcpy
>>> #Set geoprocessing environment
>>> arcpy.env.workspace = r"I:\Dr. Hines\New File Geodatabase.gdb"
>>> arcpy.env.overwriteOutput = True
>>> #Create list of all blocks
>>> fcList = arcpy.ListFeatureClasses("*blk00")
>>> #Create loop
>>> for fc in fcList:
...     X = arcpy.SelectLayerByLocation_management("Analysis Roads","HAVE_THEIR_CENTER_IN", fc)
...     highway = "Analysis Roads"
...     rows = arcpy.UpdateCursor(highway)
...     for row in rows:
...         if row is in X:
...             row.STFID = fc.STFID
...             rows.updateRow(row)
...             del row
...             del rows
					
				
			
			
				
			
			
				
			
			
			
			
			
			
		
for fc in fcList:
    X = arcpy.SelectLayerByLocation_management("Analysis Roads","HAVE_THEIR_CENTER_IN", fc)
    highway = X  #I think you want highway to = X which is the selection of analysis roads from the previous #operation? 
    rows = arcpy.UpdateCursor(highway)
    for row in rows:
        if row is in X:#I dont think this is correct if statement... should be something like if X==ROW
            row.STFID = fc.STFID
            rows.updateRow(row)
     del row #these del row, del rows should be tabbed outside of the loop, not inside
     del rows
					
				
			
			
				
			
			
				
			
			
			
			
			
			
		import arcpy
#Set geoprocessing environment
arcpy.env.workspace = r"I:\Dr. Hines\New File Geodatabase.gdb"
arcpy.env.overwriteOutput = True
#Create list of all blocks
fcList = arcpy.ListFeatureClasses("*blk00")
highway = "Analysis Roads"
#Create loop
for fc in fcList:
    arcpy.SelectLayerByLocation_management(highway,"HAVE_THEIR_CENTER_IN", fc)
    rows = arcpy.UpdateCursor(highway)
    for row in rows:
        row.STFID = fc.STFID
        rows.updateRow(row)
    del row
    del rows
					
				
			
			
				
			
			
				
			
			
			
			
			
			
		