Greetings,
I don't think there is a very easy way to get the float values directly from the Image Analysis Window right now. It is possible with a few more clicks:
Load the individual bands 3 (red) and 4 (nir) into ArcMap, with band 4 on top of band 3. Calculate the difference between them (button on Image Analysis Window) twice. The first (bottom in TOC) layer, open the layer properties > functions tab and change the math to plus. Then do another difference between the two difference layers (your building the NDVI formula in essence through the functions). This last difference (with nir - red and nir + red as input), change the math to divide and the output to 32 bit float.
Voila, you have the NDVI in float.
Robert