import arcpy
rootWorkspace = r"C:\tmp\Test.gdb"
arcpy.env.workspace = rootWorkspace
#list all feature datasets
featureDatasets = arcpy.ListDatasets("", "Feature")
for dataset in featureDatasets:
#for each feature dataset change workspace and list feature classes it contains
arcpy.env.workspace = rootWorkspace + "\\" + dataset
print "Geodatabase dataset: " + dataset
featureClasses = arcpy.ListFeatureClasses()
for fc in featureClasses:
print fc