This isnt a structures service type its a Map Image Layer (Map Service) You cannot add a group layer in a Map Image Layer to Map Viewer. This is because when adding a layer from a Map Service URL like your sample
Goes through a different pipeline and makes a singular layer that falls under a Feature Layer. A group layer is not support on feature layers so the layer you are trying to add cannot be added. If you remove the /20 or add the individual layers in that group it will work as expected.