To move the cache or set up folders and services?
For the cache files, I would just use windows explorer or the command window "xcopy" if you have a why to many. If you are using the "compact" or "bundled" format for the cache files, it's not all that bad to just drag and drop. I sometimes prefer dragging a folder at a time (if doing drag-drop) so I can monitor it. the xcopy command is very reliable too, and you can have it display the files in a "verbose" mode. i tend to think it's a bit faster than the windows explorer, but it depends on what you are comfortable with.
As for the folders and services, there are probably many ways to automate. ArcGIS Help (10.2, 10.2.1, and 10.2.2) might be a good place to start. Depending on how many folders you have (<10?), I would probably create those manually then set up a script if needed to do the other. Do a search in your browser list "arcpy create AGS services 10.2" to come up with other options.
Again, depending on how many services you have, it may be just as easy to do it manually.....but if you need to do more often, worth checking out python scripts.
