Hi,
The xml file will need to be triangulated surface for the LandXML to Tin tool to recognize it. In the tool dialog box, you would see a list of the Tins available for import. I'm not familar with Microstation enough to give you any suggestions on converting the .tin file to a LandXML file. You may want to provide more information about how you created the xml file in Microstation and what version of LandXML it is. Screenshots might help other forum goers provide you with more suggestions on that process.
Best wishes.