How to Add attachments of a feature along with attributes to PDF exported using arcpy in python.
PDFDocument—ArcPy | ArcGIS Desktop under
updateDocProperties ({pdf_title}, {pdf_author}, {pdf_subject}, {pdf_keywords}, {pdf_open_view}, {pdf_layout})
pdf_open_view
beyond the example in
PDFDocumentOpen—ArcPy | ArcGIS Desktop
which show to open with thumbnails, instead of attachments.