are you looking for the structure ? Geodatabase XML—Help | ArcGIS for Desktop
How to import it? Importing a geodatabase schema from an XML workspace document—ArcGIS Help | ArcGIS for Desktop
How to export it? Exporting a geodatabase schema to an XML workspace document—ArcGIS Help | ArcGIS for Desktop
the whitepaper? XML Schema of the Geodatabase
or this link ?? Documenting your geodatabase design—ArcGIS Help | ArcGIS for Desktop with its downloads and links
or a free external editor? (see options for editors on the web if current tools aren't sufficient
Yes, we are looking a tool lke arcgis diagrammer or a tool that can help us edit the schema experted as xml and to help us define all changes
then we can use import xml tools in arcgis
I updated the link with this Documenting your geodatabase design—ArcGIS Help | ArcGIS for Desktop there are links in there, but I haven't tried the options.
To add to what Dan has documented: A note about the use of UML for geodatabase design—ArcGIS Help | ArcGIS for Desktop there is a 3rd party tool called Sparx Enterprise Architect: ArcGIS Geodatabase Design | UML | Enterprise Architect