Samantha,To be clear, you don't actually need PythonWin to do python scripting, it is just a nice Windows based Integrated Development Environment (IDE).PythonWin is not installed by default when you install ArcGIS but should be included on the Install disc for manual install.If that is not available, then you can d/l the apropriate version from Sourceforge.net.Once it is installed make a shortcut to the executable: C:\Python26\ArcGIS10.0\Lib\site-packages\pythonwin\Pythonwin.exe
I hope that clears things up a bit.
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