I am having the same issue. Did you ever figure this out??
Does one of the layers in the data-frame have a transparency or a graphic inserted?Any layers that have a transparency enabled will cause that "white" background effect and also, exporting to a vector based format will cause the white background to show up.See: http://forums.arcgis.com/threads/21701-inserting-a-png-or-imageThe workaround was to export the map to a raster like a jpeg, png, tiff...I also found recently that if I used ArcMap's export to PDF (from File pulldown) it would show the white background.I had to "print" the map using a PDF printer driver like "Adobe PDF" which would print the layout to a pdf file and that did not show the white background.
What version including service packs are you at?
Weird, I believe I am doing the same thing but it looks to be working for me. I'm at 10.1...
What are you using to clip the data frame shape? Is it a feature class, specified extents, or something else? I used another feature class to clip and it does not have the background.
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