In my experience, the 99999 buffer error is related to the stream geometry overlapping itself or self-intersecting.I would suggest running the stream network through 'repair geometry' first and then make a topology to identify self-intersecting and self-overlapping arcs.
Like I thought, calculating land cover for each catchment individually takes a very long time. Each catchment is taking around 15 seconds. One of my smallest datasets has over 2k catchments which would mean a processing time of around 9 hours.
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