at 10, you can't get KeyField and ForeignKey Field from a relationship class.(if I'm not mistaken) starting at 10.1, those additional information including cardinality are exposed in MapServer SOAP API's RelateInfo type.click this link http://sampleserver6.arcgisonline.com/arcgis/services/Census/MapServer?wsdl and look for RelateInfo type.
I have to use Rest API to get the values for the workaround currently.
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