Hi,I looked out your public website and I looks like it is using ArcGIS Server .NET ADF. I know this is probably too technically jargen but essential it looks like you already have ArcGIS Server and have a map service- basically what this does is send to website images of map based on scale and extent requested. And it uses a ArcMap mxd or msd file to create the service..
one more thing- pmf files are typically created through a check out process in ArcMap. I am wiling to bet you there are existing mxds for those maps. I would contact the person who manages creating those pmf files. And if so- can just use those to publish to argis online.
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