You are a bit vague on the details. I am assuming that you would like to perform a supervised classification. See the following help document. http://help.arcgis.com/en/arcgisdesktop/10.0/help/index.html#//00nv00000003000000.htm
So, I have been tasked to to this in ArcGIS 10 and I am a bit clueless because it, until this point, hasn't been in my lane of assignments. The last time I did something like this it was in ERDAS Imagine, not Arc. So currently I have an orthorectified image, correct projection for the area I am working in, and all the .shp's /.lyr's I need IE: Roads, Hydrology, etc. I just don't know where to begin I guess and I haven't found a tutorial or anything relating to it which is why im reaching out here to see if anyone has worked this before.
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