Try adding your file with that shows the Null values into the ArcMap. Check to see if they are still Null in the Attribute table. Without doing anything else, try exporting the data to a DBF file. To do so right click on the table > Data > Export Data. Choose a location to export to and set the save as type to dBASE which will add the .DBF extension. When the export is done add it to the map and check the attribute table again.
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