ArcGIS Desktop on 64-bit ArcGIS Desktop 10.0 applications are natively 32-bit applications but take advantage of a technology known as large memory awareness. This means that individual processes, such as ArcMap.exe, may be capable of accessing more than 2GB of memory (up to 4GB) when run on a 64-bit OS. Note that some functionality and third-party libraries that are part of ArcGIS are not compatible with large-address-awareness, and as such, some portions of ArcGIS may not be able to address more than 2GB even when running on a 64-bit OS.
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